Flory-Huggins theory for athermal mixtures of hard spheres and larger flexible polymers
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چکیده
منابع مشابه
Flory-Huggins theory for athermal mixtures of hard spheres and larger flexible polymers.
A simple analytic theory for mixtures of hard spheres and larger polymers with excluded volume interactions is developed. The mixture is shown to exhibit extensive immiscibility. For large polymers with strong excluded volume interactions, the density of monomers at the critical point for demixing decreases as one over the square root of the length of the polymer, while the density of spheres t...
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ژورنال
عنوان ژورنال: Physical Review E
سال: 2002
ISSN: 1063-651X,1095-3787
DOI: 10.1103/physreve.66.051401